Deprotonation of Large Calixarenes – Cation Binding and Conformations
نویسندگان
چکیده
منابع مشابه
Regioselective Monoalkylation of Calixarenes. Synthesis of Homodimer Calixarenes.
The selective monoalkylation at the smaller (lower) rim of the p-tert-butylcalix[4]- and -[6]arenes using bis(butyltin)oxide and different alkylating agents is described. The procedure is remarkable for the mild conditions used allowing an efficiently access to monoalkylated calixarene derivatives in moderate to good yields. Monoalkynylcalix[4]arene and monoalkynylcalix[6]arene have been synthe...
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The synthetic models for the structures, spectroscopic properties and catalytic activities of metalloprotein active sites have been reviewed. Calixarenes were used as new biomimetic catalysts because of their advantage of providing preorganiiation of the catalytic group, which can bind the substrate dynamically that results in fast turnover and fast release of the products. Functional and struc...
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ژورنال
عنوان ژورنال: Australian Journal of Chemistry
سال: 2016
ISSN: 0004-9425
DOI: 10.1071/ch15761